Main Article Content
Abstract
The release of organic dyes is a serious concern to the water resources and the quality of the environment, and there is a strong necessity to create effective catalysts that can degrade organic dyes. Here, the nanofibers of iron (III) oxide were produced using the electrospinning technique and the high-temperature firing technique, and the oxygen vacancy defects on the surfaces of the nanofibers were formed using the reduction technique of NaBH4. The findings show that the surface oxygen vacancies significantly enhance the catalytic activity. Specifically, the Fe2O3−VO nanofibers achieved near-complete degradation of MB within 4 minutes, with a reaction rate constant (k≈0.95 min-1) approximately 68 times higher than that of pristine nanofibers. Such optimized properties not only demonstrate the potential of defect-engineered iron oxide in organic dye treatment but also provide insights into the structural design of highly effective catalysts for sustainable water remediation.
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References
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- Yang, H., Li, G., Jiang, G., Zhang, Z., & Hao, Z. (2023). Heterogeneous selective oxidation of VOCs over transition metal catalysts. Applied Catalysis B: Environmental, 325, 122384. https://doi.org/10.1016/j.apcatb.2023.122384
- Khan, W. U., Hantoko, D., Bakare, I. A., Al Shoaibi, A., Chandrasekar, S., & Hossain, M. M. (2024). Co-Ni catalysts supported on zirconia for syngas production. Fuel, 369, 131675. https://doi.org/10.1016/j.fuel.2024.131675
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- Li, Z., Ji, S., Liu, Y., Cao, X., Tian, S., Chen, Y., Niu, Z., & Li, Y. (2020). Well-Defined Materials for Heterogeneous Catalysis: From Single Atoms to Clusters and Nanoparticles. Chemical Reviews, 120(2), 623–682. https://doi.org/10.1021/acs.chemrev.9b00311
- Geng, Y., Lian, Z., Zhang, Y., Liu, J., Jin, D., & Shan, W. (2024). Heteropoly acid-grafted catalysts for efficient NOx reduction. Catalysis Science & Technology, 14, 3064–3072. https://doi.org/10.1039/D4CY00210E
- Xiang, Z., Wang, W., Zhou, F., Zhang, H., Wang, Y., Zhu, W., & Wang, H. (2024). Efficient conversion of lignin-derived phenols to cycloalkanes over bifunctional catalysts with low loading of ruthenium. Fuel Processing Technology, 256, 108073. https://doi.org/10.1016/j.fuproc.2024.108073
- Shu, D., Long, X., Zhao, P., Wang, L., Li, Z., Cheng, C., ... & Cheng, B. (2024). Flash spinning polyethylene/Fe3O4 magnetic drive fibers for oil absorption underwater. Chemical Engineering Journal, 490, 151333. https://doi.org/10.1016/j.cej.2024.151333
- Xu, Z., Liu, Y., Sun, X., Xie, X., Guan, X., Chen, C., & Ma, X. (2022). Theoretical design of Na-rich anti-perovskite as solid electrolyte: The effect of cluster anion in stability and ionic conductivity. Journal of Solid State Chemistry, 316, 123643.https://doi.org/10.1016/j.jssc.2022.123643
- Li, Y., Han, B., Bi, F., Wu, Z., & Weng, X. (2024). One-Pot Synthesis of (CrMnFeCoNi) O x High-Entropy Oxides for Efficient Catalytic Oxidation of Propane: A Promising Substitute for Noble Metal Catalysts. ACS Applied Materials & Interfaces, 16(48), 66108-66116. https://doi.org/10.1021/acsami.4c14292.s001
- Wu, Y., Ma, L., Wu, J., Song, M., Wang, C., & Lu, J. (2024). Mesoporous Sc2O3 for Biomass Valorization to Fine Chemicals. Advanced Materials, 36(15), e2311698. https://doi.org/10.1002/adma.202311698
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- Sun, J., Xia, W., Zheng, Q., Zeng, X., Liu, W., Liu, G., & Wang, P. (2020). Increased active sites on α-Fe2O3 for enhanced photo-Fenton catalytic activity. ACS Omega, 5(21), 12339–12347. https://doi.org/10.1021/acsomega.0c01072
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- Liu, H., Yang, F., Xiang, M., Cao, Y., & Wu, T. (2021). Development of multilayer polypropylene separators for lithium-ion batteries via an industrial process. Industrial & Engineering Chemistry Research, 60(30), 11611-11620. https://doi.org/10.1021/acs.iecr.1c01577
- Cen, S., Li, L., Li, Y., Wan, C., Linghu, W., & Wang, L. (2024). Low-Temperature Catalytic Transfer Hydrogenation of Biomass-Derived Furfural over Irreversibly Adsorbed and Highly Dispersed Zr (IV) Species. Inorganic Chemistry, 63(29), 13775-13784. https://doi.org/10.1021/acs.inorgchem.4c02156.s001
- Zhuang, L., Ge, L., Yang, Y., Li, M., Jia, Y., Yao, X., & Zhu, Z. (2017). Ultrathin Iron-Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction. Advanced Materials, 29(17), 1606793. https://doi.org/10.1002/adma.201606793
References
Xiao, Z., Wu, R., Shu, T., Wang, Y., & Li, L. (2023). Synthesis of Co-doped Fe metal–organic framework MIL-101 (Fe, Co) and efficient degradation of organic dyes in water. Separation and Purification Technology, 304, 122300. https://doi.org/10.1016/j.seppur.2022.122300
Ding, J., Pan, Y., Li, L., Liu, H., Zhang, Q., Gao, G., & Pan, B. (2020). Synergetic adsorption and electrochemical classified recycling of Cr(VI) and dyes in synthetic dyeing wastewater. Chemical Engineering Journal, 384, 123232. https://doi.org/10.1016/j.cej.2019.12323.
Yu, X., Zhang, J., Chen, Y., Ji, Q., Wei, Y., Niu, J., Yu, Z., & Yao, B. (2021). Ag-Cu2O composite films with enhanced photocatalytic activities for methylene blue degradation: Analysis of the mechanism and the degradation pathways. Journal of Environmental Chemical Engineering, 9(4), 106161. https://doi.org/10.1016/j.jece.2021.106161
Fan, L., Su, X., Zhu, H., Liu, H., Lou, S., Shi, Y., & Yan, S. (2023). Degradation of Methylene Blue by Hot Electrons Transfer in SnSe. Advanced Materials Interfaces, 10(11), 2202207. https://doi.org/10.1002/admi.202202207
Kong, L.-H., Wu, Y., Shen, R.-F., Zhang, W.-J., Dong, Z.-Y., Ge, W.-T., Guo, X.-J., Yan, X., Chen, Y., & Lang, W.-Z. (2022). Combination of N-doped porous carbon and g-C₃N₄ for effective removal of organic pollutants via activated peroxymonosulfate. Journal of Environmental Chemical Engineering, 10(3), Article 107808. https://doi.org/10.1016/j.jece.2022.107808
Chen, Q., Ning, S., Yang, J., Wang, L., Yin, X., Wang, X., ... & Zeng, D. (2024). In situ interfacial engineering of CeO2/Bi2WO6 heterojunction with improved photodegradation of tetracycline and organic dyes: mechanism insight and toxicity assessment. Small, 20(18), 2307304. https://doi.org/10.1002/smll.202307304
Rahimi, A. A., & Alihosseini, F. (2024). In Vivo and In Vitro Decolorization of Disperse Azo Dyes Using Aspergillus niger. Journal of Environmental Engineering, 150(9), 04024041. https://doi.org/10.1061/joeedu.eeeng-7596
Moumen, A., Belhocine, Y., Sbei, N., Rahali, S., Ali, F. A. M., Mechati, F., Hamdaoui, F., & Seydou, M. (2022). Removal of malachite green dye from aqueous solution by catalytic wet oxidation technique using Ni/Kaolin as catalyst. Molecules, 27(21), 7528. https://doi.org/10.3390/molecules27217528
Fang, D., Luo, D., Xiao, H., Li, J., Ma, L., Zi, J., & Lian, Z. (2024). Oxygen Vacancies-Mediated Z-Scheme Mechanism Promotes Synergistic Photoelectrocatalysis for Hydroxyl Radical and Singlet Oxygen-Cooperating on Selective Pollutant Degradation. ACS ES&T Engineering, 5(1), 77-85. https://doi.org/10.1021/acsestengg.4c00453.s001
Yanardağ, D., & Edebali, S. (2024). Adsorptive removal of dyes from aqueous solutions using biomass-derived activated carbon. Biomass Conversion and Biorefinery, 14, 5699–5712. https://doi.org/10.1007/s13399-023-04839-w
Ye, H., Chen, D., Li, N., Xu, Q., Li, H., He, J., & Lu, J. (2021). Polymer of intrinsic microporosity coated on a metal-organic framework composite membrane for highly efficient dye separation. Journal of Membrane Science, 637, 119619. https://doi.org/10.1016/j.memsci.2021.119619
Zheng, H., Lu, H., Li, S., Niu, J., Leong, Y. K., Zhang, W., ... & Chang, J. S. (2024). Recent advances in electrospinning-nanofiber materials used in advanced oxidation processes for pollutant degradation. Environmental Pollution, 344, 123223. https://doi.org/10.1016/j.envpol.2023.123223
He, Z., Ong, J. H., Bao, Y., & Hu, X. (2023). Chemocatalytic membranes for efficient degradation of emerging organic contaminants. Journal of Environmental Chemical Engineering, 11(3), 109548. https://doi.org/10.1016/j.jece.2023.109548
Liu, Y., Han, W. K., Chi, W., Fu, J. X., Mao, Y., Yan, X., & Gu, Z. G. (2023). One-dimensional covalent organic frameworks with atmospheric water harvesting for photocatalytic hydrogen evolution from water vapor. Applied Catalysis B: Environmental, 338, 123074. https://doi.org/10.1016/j.apcatb.2023.123074
Liu, H., Li, X., Zhang, X., Coulon, F., & Wang, C. (2023). Harnessing the power of natural minerals: a comprehensive review of their application as heterogeneous catalysts in advanced oxidation processes for organic pollutant degradation. Chemosphere, 337, 139404. https://doi.org/10.1016/j.chemosphere.2023.139404
Jiménez-González, C., Gil-Calvo, M., de Rivas, B., González-Velasco, J. R., Gutiérrez-Ortiz, J. I., & López-Fonseca, R. (2016). Oxidative steam reforming and steam reforming of methane, isooctane, and N-Tetradecane over an alumina supported spinel-derived nickel catalyst. Industrial & Engineering Chemistry Research, 55(14), 3920-3929. https://doi.org/10.1021/acs.iecr.6b00461.s001
Yang, H., Li, G., Jiang, G., Zhang, Z., & Hao, Z. (2023). Heterogeneous selective oxidation of VOCs over transition metal catalysts. Applied Catalysis B: Environmental, 325, 122384. https://doi.org/10.1016/j.apcatb.2023.122384
Khan, W. U., Hantoko, D., Bakare, I. A., Al Shoaibi, A., Chandrasekar, S., & Hossain, M. M. (2024). Co-Ni catalysts supported on zirconia for syngas production. Fuel, 369, 131675. https://doi.org/10.1016/j.fuel.2024.131675
Xie, Z., Sun, Z., Shao, B., Zhu, Y., Ma, R., Li, S., ... & Hu, J. (2024). Highly efficient hydrogenation of carbonate to methanol for boosting CO2 mitigation. Chemical Engineering Journal, 495, 153465. https://doi.org/10.1016/j.cej.2024.153465
Xie, C., Niu, Z., Kim, D., Li, M., & Yang, P. (2020). Surface and Interface Control in Nanoparticle Catalysis. Chemical Reviews, 120(2), 1184–1249. https://doi.org/10.1021/acs.chemrev.9b00220
Li, Z., Ji, S., Liu, Y., Cao, X., Tian, S., Chen, Y., Niu, Z., & Li, Y. (2020). Well-Defined Materials for Heterogeneous Catalysis: From Single Atoms to Clusters and Nanoparticles. Chemical Reviews, 120(2), 623–682. https://doi.org/10.1021/acs.chemrev.9b00311
Geng, Y., Lian, Z., Zhang, Y., Liu, J., Jin, D., & Shan, W. (2024). Heteropoly acid-grafted catalysts for efficient NOx reduction. Catalysis Science & Technology, 14, 3064–3072. https://doi.org/10.1039/D4CY00210E
Xiang, Z., Wang, W., Zhou, F., Zhang, H., Wang, Y., Zhu, W., & Wang, H. (2024). Efficient conversion of lignin-derived phenols to cycloalkanes over bifunctional catalysts with low loading of ruthenium. Fuel Processing Technology, 256, 108073. https://doi.org/10.1016/j.fuproc.2024.108073
Shu, D., Long, X., Zhao, P., Wang, L., Li, Z., Cheng, C., ... & Cheng, B. (2024). Flash spinning polyethylene/Fe3O4 magnetic drive fibers for oil absorption underwater. Chemical Engineering Journal, 490, 151333. https://doi.org/10.1016/j.cej.2024.151333
Xu, Z., Liu, Y., Sun, X., Xie, X., Guan, X., Chen, C., & Ma, X. (2022). Theoretical design of Na-rich anti-perovskite as solid electrolyte: The effect of cluster anion in stability and ionic conductivity. Journal of Solid State Chemistry, 316, 123643.https://doi.org/10.1016/j.jssc.2022.123643
Li, Y., Han, B., Bi, F., Wu, Z., & Weng, X. (2024). One-Pot Synthesis of (CrMnFeCoNi) O x High-Entropy Oxides for Efficient Catalytic Oxidation of Propane: A Promising Substitute for Noble Metal Catalysts. ACS Applied Materials & Interfaces, 16(48), 66108-66116. https://doi.org/10.1021/acsami.4c14292.s001
Wu, Y., Ma, L., Wu, J., Song, M., Wang, C., & Lu, J. (2024). Mesoporous Sc2O3 for Biomass Valorization to Fine Chemicals. Advanced Materials, 36(15), e2311698. https://doi.org/10.1002/adma.202311698
Chen, L., Zou, Y., Li, Y., Li, G., Liu, W., Zhang, H., & Peng, H. (2024). Alkali-resistant catalytic reduction of NOx over CeO2-WO3/MCM-22 supported catalyst by releasing Brønsted acid sites. Applied Catalysis B: Environment and Energy, 347, 123788.https://doi.org/10.1016/j.apcatb.2024.123788
Sun, J., Xia, W., Zheng, Q., Zeng, X., Liu, W., Liu, G., & Wang, P. (2020). Increased active sites on α-Fe2O3 for enhanced photo-Fenton catalytic activity. ACS Omega, 5(21), 12339–12347. https://doi.org/10.1021/acsomega.0c01072
Zhang, N., Li, X., Liu, Y., Long, R., Li, M., Chen, S., Qi, Z., Wang, C., Song, L., Jiang, J., & Xiong, Y. (2017). Defective Tungsten Oxide Nanosheets for Efficient Photocatalytic Hydrogen Evolution. SmallSmall, 13(33), 1701354. https://doi.org/10.1002/smll.201701354
Liu, H., Yang, F., Xiang, M., Cao, Y., & Wu, T. (2021). Development of multilayer polypropylene separators for lithium-ion batteries via an industrial process. Industrial & Engineering Chemistry Research, 60(30), 11611-11620. https://doi.org/10.1021/acs.iecr.1c01577
Cen, S., Li, L., Li, Y., Wan, C., Linghu, W., & Wang, L. (2024). Low-Temperature Catalytic Transfer Hydrogenation of Biomass-Derived Furfural over Irreversibly Adsorbed and Highly Dispersed Zr (IV) Species. Inorganic Chemistry, 63(29), 13775-13784. https://doi.org/10.1021/acs.inorgchem.4c02156.s001
Zhuang, L., Ge, L., Yang, Y., Li, M., Jia, Y., Yao, X., & Zhu, Z. (2017). Ultrathin Iron-Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction. Advanced Materials, 29(17), 1606793. https://doi.org/10.1002/adma.201606793