Biodiesel production from used cooking oil and cost appraisal for the purpose of reduction in dependence on petroleum oil in Laos
Corresponding Author(s) : Lemthong Chanphavong
Future Energy,
Vol. 2 No. 4 (2023): November 2023 Issue
Abstract
To mitigate dependence on fossil fuels, the government of Lao PDR has promoted the development of alternative fuel production in the country. Biodiesel is one of the most feasible and attractive fuels. This paper presents a lab-scale biodiesel production from used cooking oil (UCO) and its cost appraisal. This biodiesel production is based on the base-catalyzed transesterification reaction. The optimum parameter value in terms of catalyst concentration and amount of methanol is examined to achieve the best biodiesel yield. The results of this study revealed that the optimized condition for producing biodiesel from 1 liter of UCO is obtained using 12 g of KOH and 20 % of MeOH under the operating temperature of 60 °C and mixing time of 30 min. With this condition, the maximum yield of biodiesel is obtained at 91.3%. The total cost of production for 1 liter of biodiesel produced is approximately 17782 LAK. Production quantity at break-even point is about 41989 liters, achieving a payback period of 2.67 years.
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- Han Phoumin, Lao PDR Energy Outlook 2020, Chapter 1 Introduction, 2020. eria.org/uploads/media/Research-Project-Report/Lao-Energy-Outlook-2020/Lao-PDR-Energy-Outlook-2020.pdf.
- S. Kham, M. Bouathep, P. Phouvong, K. Southone, I. Keophayvan, Status and potential for the development of biofuels and rural renewable energy The Lao People’s Democratic Republic, 2009.
- USEPA, Oil Spills Prevention and Preparedness Regulations, (n.d.). https://www.epa.gov/emergency-response/vegetable-oils-and-animal-fats (accessed October 24, 2022).
- A.S. Elgharbawy, W.A. Sadik, O.M. Sadek, M.A. Kasaby, A review on biodiesel feedstocks and production technologies, J. Chil. Chem. Soc. 65 (2021) 5098–5109. https://doi.org/10.4067/S0717-97072021000105098.
- B.R. Moser, Biodiesel production, properties, and feedstocks, Vitr. Cell. Dev. Biol. - Plant. 45 (2009) 229–266. https://doi.org/10.1007/s11627-009-9204-z.
- M.K. Lam, K.T. Lee, A.R. Mohamed, Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review, Biotechnol. Adv. 28 (2010) 500–518. https://doi.org/10.1016/j.biotechadv.2010.03.002.
- K. Al-attab, A. Wahas, N. Almoqry, S. Alqubati, Biodiesel production from waste cooking oil in Yemen: a techno-economic investigation, Biofuels. 8 (2017) 17–27. https://doi.org/10.1080/17597269.2016.1196326.
- V. Innocenzi, M. Prisciandaro, Technical feasibility of biodiesel production from virgin oil and waste cooking oil: Comparison between traditional and innovative process based on hydrodynamic cavitation, Waste Manag. 122 (2021) 15–25. https://doi.org/10.1016/j.wasman.2020.12.034.
- C.D. Mandolesi De Araújo, C.C. De Andrade, E. De Souza E Silva, F.A. Dupas, Biodiesel production from used cooking oil: A review, Renew. Sustain. Energy Rev. 27 (2013) 445–452. https://doi.org/10.1016/j.rser.2013.06.014.
- A. Mohammadshirazi, A. Akram, S. Rafiee, E. Bagheri Kalhor, Energy and cost analyses of biodiesel production from waste cooking oil, Renew. Sustain. Energy Rev. 33 (2014) 44–49. https://doi.org/10.1016/j.rser.2014.01.067.
- Z. Yaakob, M. Mohammad, M. Alherbawi, Z. Alam, K. Sopian, Overview of the production of biodiesel from Waste cooking oil, Renew. Sustain. Energy Rev. 18 (2013) 184–193. https://doi.org/10.1016/j.rser.2012.10.016.
- S. Joshi, P. Hadiya, M. Shah, A. Sircar, Techno-economical and Experimental Analysis of Biodiesel Production from Used Cooking Oil, 7 (2019) 2–7. https://doi.org/10.1007/s41247-018-0050-7.
- B.H.H. Goh, C.T. Chong, Y. Ge, H.C. Ong, J.H. Ng, B. Tian, V. Ashokkumar, S. Lim, T. Seljak, V. Józsa, Progress in utilisation of waste cooking oil for sustainable biodiesel and biojet fuel production, Energy Convers. Manag. 223 (2020). https://doi.org/10.1016/j.enconman.2020.113296.
- M.K. Pasha, L. Dai, D. Liu, M. Guo, W. Du, An overview to process design, simulation and sustainability evaluation of biodiesel production, Biotechnol. Biofuels. 14 (2021) 1–23. https://doi.org/10.1186/s13068-021-01977-z.
- M.R. Khodadadi, I. Malpartida, C.W. Tsang, C.S.K. Lin, C. Len, Recent advances on the catalytic conversion of waste cooking oil, Mol. Catal. 494 (2020) 111128. https://doi.org/10.1016/j.mcat.2020.111128.
- Y. Liu, X. Yang, A. Adamu, Z. Zhu, Economic evaluation and production process simulation of biodiesel production from waste cooking oil, Curr. Res. Green Sustain. Chem. 4 (2021) 100091. https://doi.org/10.1016/j.crgsc.2021.100091.
- P.T.A. Samad, M.S. Perdani, D.N. Putri, H. Hermansyah, Techno-economic analysis of portable plant from waste cooking oil, Energy Procedia. 153 (2018) 263–268. https://doi.org/10.1016/j.egypro.2018.10.062.
- A.A.S.A. El-gharabawy, Cost Analysis for Biodiesel Production from Waste Cooking Oil Plant in Egypt, Int. J. Smart Grid. 1 (2017). https://doi.org/10.20508/ijsmartgrid.v1i1.2.g2.
- S.K. Karmee, R.D. Patria, C.S.K. Lin, Techno-economic evaluation of biodiesel production from waste cooking oil—a case study of Hong Kong, Int. J. Mol. Sci. 16 (2015) 4362–4371. https://doi.org/10.3390/ijms16034362.
- J.B. Hirkude, J. Randhir, V.W. Belokar, Techno-economic conversion of Waste Fried Oil into Biodiesel through Transesterification, IOP Conf. Ser. Mater. Sci. Eng. 377 (2018). https://doi.org/10.1088/1757-899X/377/1/012160.
- Y. Zhang, M.A. Dubé, D.D. McLean, M. Kates, Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis, Bioresour. Technol. 90 (2003) 229–240. https://doi.org/10.1016/S0960-8524(03)00150-0.
- I.A. Musa, The effects of alcohol to oil molar ratios and the type of alcohol on biodiesel production using transesterification process, Egypt. J. Pet. 25 (2016) 21–31. https://doi.org/10.1016/j.ejpe.2015.06.007.
- O.A. Aworanti, A.. Ajani, S.E. Agary, K.A. Babatunde, O.D. Akinwumi, Evaluation of Process Parameters for Biodiesel Production from Vegetable and Palm Waste Frying Oils Using a Homogeneous Catalyst, Int. J. Energy Eng. 2019 (2019) 25–35. https://doi.org/10.5923/j.ijee.20190902.01.
References
Han Phoumin, Lao PDR Energy Outlook 2020, Chapter 1 Introduction, 2020. eria.org/uploads/media/Research-Project-Report/Lao-Energy-Outlook-2020/Lao-PDR-Energy-Outlook-2020.pdf.
S. Kham, M. Bouathep, P. Phouvong, K. Southone, I. Keophayvan, Status and potential for the development of biofuels and rural renewable energy The Lao People’s Democratic Republic, 2009.
USEPA, Oil Spills Prevention and Preparedness Regulations, (n.d.). https://www.epa.gov/emergency-response/vegetable-oils-and-animal-fats (accessed October 24, 2022).
A.S. Elgharbawy, W.A. Sadik, O.M. Sadek, M.A. Kasaby, A review on biodiesel feedstocks and production technologies, J. Chil. Chem. Soc. 65 (2021) 5098–5109. https://doi.org/10.4067/S0717-97072021000105098.
B.R. Moser, Biodiesel production, properties, and feedstocks, Vitr. Cell. Dev. Biol. - Plant. 45 (2009) 229–266. https://doi.org/10.1007/s11627-009-9204-z.
M.K. Lam, K.T. Lee, A.R. Mohamed, Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review, Biotechnol. Adv. 28 (2010) 500–518. https://doi.org/10.1016/j.biotechadv.2010.03.002.
K. Al-attab, A. Wahas, N. Almoqry, S. Alqubati, Biodiesel production from waste cooking oil in Yemen: a techno-economic investigation, Biofuels. 8 (2017) 17–27. https://doi.org/10.1080/17597269.2016.1196326.
V. Innocenzi, M. Prisciandaro, Technical feasibility of biodiesel production from virgin oil and waste cooking oil: Comparison between traditional and innovative process based on hydrodynamic cavitation, Waste Manag. 122 (2021) 15–25. https://doi.org/10.1016/j.wasman.2020.12.034.
C.D. Mandolesi De Araújo, C.C. De Andrade, E. De Souza E Silva, F.A. Dupas, Biodiesel production from used cooking oil: A review, Renew. Sustain. Energy Rev. 27 (2013) 445–452. https://doi.org/10.1016/j.rser.2013.06.014.
A. Mohammadshirazi, A. Akram, S. Rafiee, E. Bagheri Kalhor, Energy and cost analyses of biodiesel production from waste cooking oil, Renew. Sustain. Energy Rev. 33 (2014) 44–49. https://doi.org/10.1016/j.rser.2014.01.067.
Z. Yaakob, M. Mohammad, M. Alherbawi, Z. Alam, K. Sopian, Overview of the production of biodiesel from Waste cooking oil, Renew. Sustain. Energy Rev. 18 (2013) 184–193. https://doi.org/10.1016/j.rser.2012.10.016.
S. Joshi, P. Hadiya, M. Shah, A. Sircar, Techno-economical and Experimental Analysis of Biodiesel Production from Used Cooking Oil, 7 (2019) 2–7. https://doi.org/10.1007/s41247-018-0050-7.
B.H.H. Goh, C.T. Chong, Y. Ge, H.C. Ong, J.H. Ng, B. Tian, V. Ashokkumar, S. Lim, T. Seljak, V. Józsa, Progress in utilisation of waste cooking oil for sustainable biodiesel and biojet fuel production, Energy Convers. Manag. 223 (2020). https://doi.org/10.1016/j.enconman.2020.113296.
M.K. Pasha, L. Dai, D. Liu, M. Guo, W. Du, An overview to process design, simulation and sustainability evaluation of biodiesel production, Biotechnol. Biofuels. 14 (2021) 1–23. https://doi.org/10.1186/s13068-021-01977-z.
M.R. Khodadadi, I. Malpartida, C.W. Tsang, C.S.K. Lin, C. Len, Recent advances on the catalytic conversion of waste cooking oil, Mol. Catal. 494 (2020) 111128. https://doi.org/10.1016/j.mcat.2020.111128.
Y. Liu, X. Yang, A. Adamu, Z. Zhu, Economic evaluation and production process simulation of biodiesel production from waste cooking oil, Curr. Res. Green Sustain. Chem. 4 (2021) 100091. https://doi.org/10.1016/j.crgsc.2021.100091.
P.T.A. Samad, M.S. Perdani, D.N. Putri, H. Hermansyah, Techno-economic analysis of portable plant from waste cooking oil, Energy Procedia. 153 (2018) 263–268. https://doi.org/10.1016/j.egypro.2018.10.062.
A.A.S.A. El-gharabawy, Cost Analysis for Biodiesel Production from Waste Cooking Oil Plant in Egypt, Int. J. Smart Grid. 1 (2017). https://doi.org/10.20508/ijsmartgrid.v1i1.2.g2.
S.K. Karmee, R.D. Patria, C.S.K. Lin, Techno-economic evaluation of biodiesel production from waste cooking oil—a case study of Hong Kong, Int. J. Mol. Sci. 16 (2015) 4362–4371. https://doi.org/10.3390/ijms16034362.
J.B. Hirkude, J. Randhir, V.W. Belokar, Techno-economic conversion of Waste Fried Oil into Biodiesel through Transesterification, IOP Conf. Ser. Mater. Sci. Eng. 377 (2018). https://doi.org/10.1088/1757-899X/377/1/012160.
Y. Zhang, M.A. Dubé, D.D. McLean, M. Kates, Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis, Bioresour. Technol. 90 (2003) 229–240. https://doi.org/10.1016/S0960-8524(03)00150-0.
I.A. Musa, The effects of alcohol to oil molar ratios and the type of alcohol on biodiesel production using transesterification process, Egypt. J. Pet. 25 (2016) 21–31. https://doi.org/10.1016/j.ejpe.2015.06.007.
O.A. Aworanti, A.. Ajani, S.E. Agary, K.A. Babatunde, O.D. Akinwumi, Evaluation of Process Parameters for Biodiesel Production from Vegetable and Palm Waste Frying Oils Using a Homogeneous Catalyst, Int. J. Energy Eng. 2019 (2019) 25–35. https://doi.org/10.5923/j.ijee.20190902.01.