Socio-energetic stamina in photovoltaics: material security and distributed manufacturing potential of Kesterite (CZTSSe)
Corresponding Author(s) : Coskun Firat
Future Energy,
Vol. 5 No. 2 (2026): In Press
Abstract
Energy transitions face a materials paradox because solar resources are widely distributed, but photovoltaic systems require supply chains that operate from specific geographic locations and rely on certain thin-film technologies that use rare byproduct metals. The study investigates kesterite photovoltaics (Cu2ZnSn(S,Se)4; CZTSSe) as an energy solution for locations facing energy insecurity that require policies that go beyond cost-effective electricity to include supply security, manufacturing access, and dependable service delivery. We develop a multi-criteria assessment combining (i) indicators of mineral scarcity and refining concentration, (ii) benchmarked manufacturing capital intensity with scale adjustment, and (iii) scenario-based techno-economic analysis that incorporates grid unreliability through avoided outage costs (VoLL). Refining concentration for indium and gallium is extreme (HHI > 6,000), whereas key CZTSSe constituents exhibit substantially lower concentration. A 30 TW deployment stress test indicates that large-scale CIGS expansion faces severe indium constraints even under optimistic recycling, while for CZTSSe, the binding concern shifts toward tin reserve definitions, reserve growth, and end-of-life recovery for bulk metals. We introduce socio-energetic stamina as a development-relevant lens for comparing PV options by material security, manufacturability, and operational resilience, clarifying where efficiency-first evaluation can misrank technologies when reliability and import dependence shape real-world energy access outcomes.
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Goldschmidt, J. C., Wagner, L., Pietzcker, R., & Friedrich, L. (2021). Technological learning for resource efficient terawatt scale photovoltaics. Energy & Environmental Science, 14(10), 5147–5160. https://doi.org/10.1039/d1ee02497c.
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Mitzi, D. B., Gunawan, O., Todorov, T. K., Wang, K., & Guha, S. (2011). The path towards a high-performance solution-processed kesterite solar cell. Solar Energy Materials and Solar Cells, 95(6), 1421-1436. https://doi.org/10.1016/j.solmat.2010.11.028
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Houimi, A., Gezgin, S. Y., Mercimek, B., & Kılıç, H. Ş. (2021). Numerical analysis of CZTS/n-Si solar cells using SCAPS-1D. A comparative study between experimental and calculated outputs. Optical Materials, 121, 111544. https://doi.org/10.1016/j.optmat.2021.111544.
Schorr, S. (2011). The crystal structure of kesterite type compounds: A neutron and X-ray diffraction study. 95(6), 1482–1488. https://doi.org/10.1016/j.solmat.2011.01.002.
Chen, S., Walsh, A., Yang, J., Gong, X., Sun, L., Yang, P., Chu, J., & Wei, S.-H. (2011). Compositional dependence of structural and electronic properties of Cu2ZnSn(S,Se)4alloys for thin film solar cells. 83(12). https://doi.org/10.1103/physrevb.83.125201.
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Maughan, A. E., Ganose, A. M., Scanlon, D. O., & Neilson, J. R. (2019). Perspectives and Design Principles of Vacancy-Ordered Double Perovskite Halide Semiconductors. Chemistry of Materials, 31(4), 1184–1195. https://doi.org/10.1021/acs.chemmater.8b05036.
Bazilian, M., Nussbaumer, P., Rogner, H.-H., Brew-Hammond, A., Foster, V., Pachauri, S., Williams, E., Howells, M., Niyongabo, P., Musaba, L., Gallachóir, B. Ó., Radka, M., & Kammen, D. M. (2012). Energy access scenarios to 2030 for the power sector in sub-Saharan Africa. Utilities Policy, 20(1), 1–16. https://doi.org/10.1016/j.jup.2011.11.002.
Domegni, K. M. S., & Azouma, Y. O. (2022). Productive uses of energy: A solution for promoting energy justice in rural areas in West Africa. Renewable and Sustainable Energy Reviews, 160, 112298. https://doi.org/10.1016/j.rser.2022.112298.
Sen, A. (2001). Development as Freedom. OUP Oxford. ISBN: 0192893300.[27] Nussbaum, M. C. (2011). Creating Capabilities: The Human Development Approach. Harvard University Press. https://doi.org/10.2307/j.ctt2jbt31
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Sun, H., Meng Zhenghao, Meilin, L., Yang, X., & Wang Xiaoxue. (2023). Global supply sustainability assessment of critical metals for clean energy technology. Resources Policy, 85, 103994–103994. https://doi.org/10.1016/j.resourpol.2023.103994.
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